ZINC MEDIATED ALLYLATION OF ALDEHYDES AND KETONES USING ALLYL BROMIDES AND COMMERCIAL ZINC DUST - THE ISSUE OF REGIOSELECTIVITY AND STEREOSELECTIVITY

Authors
MAJEE A DAS AR RANU BC
Citation
A. Majee et al., ZINC MEDIATED ALLYLATION OF ALDEHYDES AND KETONES USING ALLYL BROMIDES AND COMMERCIAL ZINC DUST - THE ISSUE OF REGIOSELECTIVITY AND STEREOSELECTIVITY, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 37(8), 1998, pp. 731-736
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry → ACNP
ISSN journal
03764699
Volume
37
Issue
8
Year of publication
1998
Pages
731 - 736
Database
ISI
SICI code
0376-4699(1998)37:8<731:ZMAOAA>2.0.ZU;2-M
Abstract
An efficient procedure for the preparation of homoallylic alcohols has been achieved by a simple reaction of an aldehyde or a ketone with al lyl bromide and commercial zinc dust in tetrahydrofuran. Excellent reg ioselectivity has been observed in the reaction of substituted allyl b romides.