The structure and morphology of Sb-covered Ge(001) surfaces has been s
tudied with scanning tunneling microscopy and low-energy electron diff
raction. After deposition of submonolayers of Sb at room temperature a
nd annealing at 350 degrees C, the images show an interfacial mixing o
f symmetrical Sb dimers and Ge dimers. At saturation coverage, the (2
x I) reconstruction exhibits a high density of antiphase domain bounda
ries. Upon annealing at temperatures between 480 and 510 degrees C the
morphology of the surface changes drastically without Sb desorption.
Oriented two-dimensional islands and vacancies are formed which have d
istinctive shapes. The rearrangements which occur on the surface can b
e understood in terms of stress domains, which reduce the surface stre
ss.