A NEW AND EFFICIENT ELECTROSYNTHESIS OF POLYSUBSTITUTED CYCLOPROPYLPHOSPHONATES, USING ELECTROCHEMICALLY ACTIVATED MAGNESIUM

Authors
JUBAULT P GOUMAIN S FEASSON C COLLIGNON N
Citation
P. Jubault et al., A NEW AND EFFICIENT ELECTROSYNTHESIS OF POLYSUBSTITUTED CYCLOPROPYLPHOSPHONATES, USING ELECTROCHEMICALLY ACTIVATED MAGNESIUM, Tetrahedron, 54(49), 1998, pp. 14767-14778
Citations number
41
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
49
Year of publication
1998
Pages
14767 - 14778
Database
ISI
SICI code
0040-4020(1998)54:49<14767:ANAEEO>2.0.ZU;2-X
Abstract
The diastereoselective electrosynthesis of polysubstituted a-chloro cy clopropylphosphonates is efficiently achieved by electroreduction of d iisopropropyl trichloromethylphosphonate in the presence of Michael ac cepters, in a one-compartment cell equipped with a magnesium sacrifici al anode. (C) 1998 Elsevier Science Ltd. All rights reserved.