The results of a photoelectron spectroscopy study of the K/GaP(110) in
terface grown at T=120 K are presented for the first time. The analysi
s shows a big core level shift at lower binding energies (Delta E=1.6
eV at a coverage theta=0.1 ML) for the P 2p core level spectra. We int
erpret this result in terms of a charge redistribution affecting both
types of atoms of the first substrate layer, suggesting some differenc
es from the intuitive picture of strong ionic localised bonding betwee
n the alkali and the surface Ga atom.