DIASTEREOSELECTIVE SYNTHESIS OF THE MODEL INSECT ANTIFEEDANTS RELATEDTO AZADIRADIONE AND EPOXYAZADIRADIONE BASED ON INTRAMOLECULAR INSERTION OF ALPHA-ARYL-ALPHA-DIAZOKETONES

Authors
FERNANDEZMATEOS A COCA GP ALONSO JJP GONZALEZ RR SIMMONDS MSJ BLANEY WM
Citation
A. Fernandezmateos et al., DIASTEREOSELECTIVE SYNTHESIS OF THE MODEL INSECT ANTIFEEDANTS RELATEDTO AZADIRADIONE AND EPOXYAZADIRADIONE BASED ON INTRAMOLECULAR INSERTION OF ALPHA-ARYL-ALPHA-DIAZOKETONES, Tetrahedron, 54(49), 1998, pp. 14989-14998
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
49
Year of publication
1998
Pages
14989 - 14998
Database
ISI
SICI code
0040-4020(1998)54:49<14989:DSOTMI>2.0.ZU;2-U
Abstract
A new practical and stereoselective method for the synthesis of the mo del insect antifeedant CDE fragment of azadiradione and epoxyazadiradi one, based on intramolecular insertion of alpha-aryl-alpha-diazoketone s, has been developed. The procedure can be applied to complex systems . A short SAR study is reported (C) 1998 Elsevier Science Ltd. All rig hts reserved.