We report a Cu 2p X-ray absorption spectroscopy (XAS) study of Cu pseu
domorphic epilayers grown on Ag(001) as a function of the Cu coverage
from the sub-monolayer up to similar to 3.6 ML. The thus-probed Cu 3d
unoccupied distribution of states local to the Cu sites is found to ex
hibit a strong similarity in the shape with respect to bcc ultrathin C
u films grown on Fe(001). In addition, the spectra change as the overl
ayer is progressively increased thereby reflecting the evolution of th
e structural properties.