PRACTICAL AND VERSATILE SYNTHESES OF ANGULAR HYDROXYMETHYLATED DECALONES

Authors
SUH YG KIM HS KUMAR PR CHOI NS JUNG JK
Citation
Yg. Suh et al., PRACTICAL AND VERSATILE SYNTHESES OF ANGULAR HYDROXYMETHYLATED DECALONES, Tetrahedron, 54(50), 1998, pp. 15161-15166
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
50
Year of publication
1998
Pages
15161 - 15166
Database
ISI
SICI code
0040-4020(1998)54:50<15161:PAVSOA>2.0.ZU;2-4
Abstract
The practical and versatile syntheses of angular hydroxymethylated dec alones as potential synthetic intermediates for terpenoids are describ ed. Particularly angular hydroxymethylated bicyclodecanedione 1 has be en synthesized in 45 % overall yield from methyl 2,6-dimethoxy-1,4-dih ydrobenzoate via six step sequence. (C) 1998 Elsevier Science Ltd. All rights reserved.