FE(III) MEDIATED OXIDATIVE RADICAL CYCLIZATION OF CYCLOPROPANONE ACETALS

Citation
Ki. Bookermilburn et al., FE(III) MEDIATED OXIDATIVE RADICAL CYCLIZATION OF CYCLOPROPANONE ACETALS, Tetrahedron, 54(50), 1998, pp. 15321-15344
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404020
Volume
54
Issue
50
Year of publication
1998
Pages
15321 - 15344
Database
ISI
SICI code
0040-4020(1998)54:50<15321:FMORCO>2.0.ZU;2-5
Abstract
A variety of cyclopropanone acetal derivatives were found to undergo f acile Fe(III) mediated oxidative radical cyclisation to the correspond ing trisubstituted cyclopentane esters in good yield and with diastere oselectivities as high as 23:1. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.