Laser surface remelting at various velocities has been employed to stu
dy the selection of microstructures of high-purity Fe-C-Si alloys cont
aining nominally 3.2 to 4.2 wt.% C and 1 to 3 wt.% Si. The microstruct
ure of the remelted region consisted of metastable Fe-Fe3C eutectic (l
edeburite) or austenite dendrites, with interdendritic eutectic. Furth
ermore, ledeburite presents two solid-liquid interface morphologies: p
lanar and cellular. The competition between the austenite dendrites an
d the ledeburite eutectic as a function of solidification rate has bee
n experimentally determined. The critical velocity which destabilizes
the planar Fe-Fe3C eutectic with respect to primary austenite dendrite
s, was of the order of several mm/s and depends on the initial composi
tion of the alloy. The critical velocity for the destabilization of th
e eutectic interface leading to two-phase cells was 0.44 mm/s, for the
alloy containing 4.2 wt.% C and 1 wt.% Si. Theoretical calculations o
f the coupled zone have been performed using current microstructure se
lection models. The results of the simulation were then used to constr
uct a microstructure map which was compared with experimental results.