We have studied the electronic and magnetic structure of ultrathin Mn
films grown on 3d transition metal surfaces using X-ray absorption and
resonant photoemission. At submonolayer coverages Mn deposition leads
to a highly localized 3d(5)-like ground state, A delocalized metallic
ground state is formed upon increasing Mn-Mn 3d orbital overlap after
percolation of the film. A similar state can also be formed through h
ybridization between Mn and substrate 3d states even at very low cover
ages. As shown by magnetic circular dichroism Mn exhibits long-range f
erromagnetic order only in the latter systems, which evidences the imp
ortance of 3d hybridization for exchange coupling.