We report the results of a scanning tunneling microscopy investigation
of the initial process of bismuth thin-film growth on Si(100) surface
s. Bismuth atoms adsorbed on the Si(100) surface at 400 degrees C form
a film of diamond-like structure with a thickness of more than 2 laye
rs, under the influence of the substrate structure. The top layer of t
he bismuth film shows (2 x n) (n similar or equal to 6) periodicity. I
n a bismuth desorption process, a new surface phase appears, which has
linear chains of bismuth dimers perpendicular to substrate-Si step ed
ges.