J. Gutzmer et Nj. Beukes, THE MANGANESE FORMATION OF THE NEOPROTEROZOIC PENGANGA GROUP, INDIA -REVISION OF AN ENIGMA, Economic geology and the bulletin of the Society of Economic Geologists, 93(7), 1998, pp. 1091-1102
A thin but laterally extensive stratiform manganese formation interbed
ded with limestone, of the Neoproterozoic Penganga Group near Adilabad
in Andhra Pradesh, India, which has been described in literature as p
rimary sedimentary oxide deposit, has recently been found to have deve
loped fron a manganese carbonate protore composed of laminated and mic
rooidal rhodochrosite and kutnohorite. Models for the origin of the or
e thus have to be revised. Sedimentological evidence suggests that the
manganese was deposited on the outer shelf of a carbonate platform fo
llowing a major transgression. Petrographic and geochemical evidence i
s provided showing that the carbonate microoids originated immediately
below the sediment-water interface during very early diagenesis. Micr
obially mediated suboxic diagenesis and reduction of hydrogenetically
precipitated Mn4+ oxihydroxides by organic carbon were instrumental in
the formation of the manganese carbonates.