The Si(100)-(2 x 1) surface is studied after interaction with SiH4 und
er UHV-CVD conditions between 550 and 690 K with high-resolution scann
ing tunneling microscopy. Ln this temperature region, new metastable c
ross-shaped structural tetramer units are formed in addition to small
Si islands and patches of hydrogen-terminated substrate. These tetrame
rs are interpreted as a combination of four SiH2 groups connecting fou
r Si substrate atoms.