With the aim of using fullerene thin films as potential encapsulating
material in surface reconstructions, we have studied the monolayer roo
m temperature adsorption of C-60 on Si(111)root 3 x root 3 R(30 degree
s)-Ag surfaces using Auger electron spectroscopy as well as high resol
ution synchrotron radiation core-level spectroscopy. The thermal stabi
lity of the encapsulating layers has also been studied: upon heating,
a replacement reaction takes place between silver and C-60. Silver des
orbs completely around 550 degrees C and a strongly bound C-60 monolay
er remains on top of the silicon surface.