A detailed mathematical analysis is undertaken of solitary-wave soluti
ons of a system of coupled nonlinear Schrodinger equations describing
second-harmonic generation in optical materials with chi((2)) nonlinea
rity. The so-called bright-bright case is studied exclusively. The sys
tem depends on a single dimensionless parameter a that includes both w
ave and material properties. Using methods from the calculus of variat
ions, the first rigorous mathematical proof is given that at least one
solitary wave exists for all positive a. Recently, bound states (mult
ipulsed solitary waves) have been found numerically. Using numerical c
ontinuation, the region of existence of these solutions is revealed to
be alpha is an element of (0, 1), and the bifurcations occurring at t
he two extremes of this interval are uncovered.