Dhs. Ramkumar et al., COMPUTATION OF THE LINEAR VISCOELASTIC RELAXATION SPECTRUM FROM EXPERIMENTAL-DATA, Journal of applied polymer science, 64(11), 1997, pp. 2177-2189
Accurate and reliable determination of the linear viscoelastic relaxat
ion spectrum is a critical step in the application of any constitutive
equation. The experimental data used to determine the relaxation spec
trum always include noise and are over a limited time or frequency ran
ge, both of which can affect the determination of the spectrum. Regula
rization with quadratic programming has been used to derive the spectr
um; however, because both the experimental data and the spectrum chang
e by more than an order of magnitude, the input data and the spectrum
are normalized in order for the numerical procedure to be accurate. Ac
curate determination of the relaxation spectrum requires that the spec
trum extend about two logarithmic decades on either side of the freque
ncy range of the input data. The spectrum calculated from G '' alone i
s more accurate at shorter relaxation times, while that from G' data a
lone is more accurate at longer relaxation times. Therefore, for best
results, the spectrum is obtained from a combination of G' and G '' da
ta, blended in the manner described herein. Comparison with existing m
ethods in the literature shows a consistently improved performance of
the present method illustrated with both model as well as experimental
data. (C) 1997 John Wiley & Sons, Inc.