The closure of the loop of pulp mills means that not only the pulping
chemicals and the alkali used in the bleach plant have to be recovered
, but in addition non-process elements have to be removed from the cyc
le. For closing the loop, it is important to perform pulp bleaching wh
ile maintaining a homogeneous pH and temperature profile in the differ
ent stages. These prerequisites can be achieved more easily in TCF tha
n in ECF bleaching. The application of catalysts in peroxide containin
g bleaching stages renders possible a bleaching sequence which accompl
ishes these prerequisites. The fully bleached pulps have brightnesses
which correspond to the market re-quirements, and their strength prope
rties are equivalent to those of ECF-bleached pulps. For ASAM as well
as for Kraft pulping the replacement of black liquor burning in a redu
cing atmosphere by a pyrolysis technique is favorable. By splitting th
e process chemicals into sodium and sulphur compounds it is possible t
o apply consequently the principles of extended delignification, and a
ll bleaching stages can be supplied with alkali In the ASAM process, t
he application of pyrolysis technique facilitates the chemical recover
y process.