SUBSTITUTED DIAZACROWN ETHERS - SYNTHESIS, SPECTRAL CHARACTERIZATION AND SINGLE-CRYSTAL STRUCTURES OF C20H42N2O8(NAI)(2)CENTER-DOT-H2O AND C20H42N3O8(KI)(2)CENTER-DOT-H2O

Authors
KILIC Z YILDIZ M HOKELEK T ERDOGAN B
Citation
Z. Kilic et al., SUBSTITUTED DIAZACROWN ETHERS - SYNTHESIS, SPECTRAL CHARACTERIZATION AND SINGLE-CRYSTAL STRUCTURES OF C20H42N2O8(NAI)(2)CENTER-DOT-H2O AND C20H42N3O8(KI)(2)CENTER-DOT-H2O, Journal of the Chemical Society. Dalton transactions (Print), (21), 1998, pp. 3635-3639
Citations number
42
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions (Print) → ACNP
ISSN journal
03009246
Issue
21
Year of publication
1998
Pages
3635 - 3639
Database
ISI
SICI code
0300-9246(1998):21<3635:SDE-SS>2.0.ZU;2-I
Abstract
Two N,N'-bis(2-hydroxyethyl) diaza-24-crown-8 potassium and sodium com plexes have been prepared by a one-step reaction of ethanolamine with 1,11-dichloro-3,6,9-trioxaundecane. Their structures are ascertained b y elemental analyses,H-1,C-13 NMR and FTIR spectra. To corroborate fur ther the structure assignments single-crystal structures of the comple xes ,19-hexaoxa-10,22-diazacyclotetracosane-bis(sodium iodide) monohyd rate and -bis(potassium iodide) monohydrate were determined. The struc tural features of the complexes are compared with each other and those of diazacrown ethers and cryptates.