L. Gonzalez et al., SPRINGHILL FORMATION, MAGELLAN BASIN, CHILE - FORMATION WATER CHARACTERISTICS AND MINERALOGY, Marine and petroleum geology, 15(7), 1998, pp. 651-666
The Early Cretaceous Springhill Formation is a transgressive sequence
of quartz sandstones with intercalations of shale and represents the p
rincipal hydrocarbon producer of the Magellan Basin. Analyses of its f
ormation waters from the Chilean sector (surface area approximately 20
,000 km(2)) are classified and linked to the diagenetic alteration of
the formation. Local delta(18)O determinations and core leaching have
been carried out to evaluate homogeneity and whole rock contribution t
o Springhill Formation fluid phases. Formation waters are of the chlor
ine-calcium type with Na+/Cl- < 1, (Na+ -Cl-)/SO42- < 0 and (Cl- -Na+)
/Mg2+ > 1. Together with an increase in organic maturity (Ro) between
2000 and 4000 m, a change is observed from authigenic kaolinite to ill
ite and corrensite, accompanied by a loss of porosity and permeability
. With respect to the distribution of the authigenic pore phyllosilica
tes, the shallowest kaolinite dominated area is limited by faults agai
nst deeper sectors where corrensite and illite/smectite prevail. A lat
er influx of high salinity fluids into the kaolinite area from the bas
in centre or continental graben sediments has let to the present day d
istribution of formation waters. Low scatter delta(18)O ratios of kaol
inite and corrensite reflect lithological consistency on a m-scale. Re
sidual salt analyses shows a direct relationship between the dissoluti
on of Ca and a high CaO content in the whole rock sample. (C) 1998 Els
evier Science Ltd. All rights reserved.