GASEOUS CL-3(- A JOINT MASS-SPECTROMETRIC AND THEORETICAL-STUDY() ANDCL2F+ CATIONS )

Authors
CACACE F DEPETRIS G PEPI F ROSI M SGAMELLOTTI A
Citation
F. Cacace et al., GASEOUS CL-3(- A JOINT MASS-SPECTROMETRIC AND THEORETICAL-STUDY() ANDCL2F+ CATIONS ), Rapid communications in mass spectrometry, 12(23), 1998, pp. 1911-1913
Citations number
36
Categorie Soggetti
Spectroscopy,"Chemistry Analytical
Journal title
Rapid communications in mass spectrometry → ACNP
ISSN journal
09514198
Volume
12
Issue
23
Year of publication
1998
Pages
1911 - 1913
Database
ISI
SICI code
0951-4198(1998)12:23<1911:GCAJMA>2.0.ZU;2-C
Abstract
The Cl-3(+) cation was obtained by chlorine chemical ionization (Cl-2/ Cl) via the exothermic reaction of Cl+ transfer from Cl2H+ to chlorine or by the endothermic reaction of Cl-2(+.) with chlorine, whereas Cl2 F+ was obtained from the reaction of XeF+ with chlorine. Both cations were structurally and energetically characterized by Fourier transform ion cyclotron resonance mass spectrometry and theoretical calculation s at the B3LYP/6-311++G(3df,3pd)// CCSD(T)/cc-pVQZ levels of theory. ( C) 1998 John Wiley & Sons, Ltd.