Sa. Kiselev et al., COLD PHOTOCONDUCTIVITY IN A SYSTEM OF INTERACTING CHARGE-TRANSFER EXCITONS AT A DONOR-ACCEPTOR INTERFACE, Chemical physics, 238(3), 1998, pp. 365-372
Computer simulations are used to investigate the phase transition to t
he conducting state in a system of interacting 2D charge-transfer exci
tons (CTEs) at a donor-acceptor interface. The phase transition arises
due to strong dipole-dipole repulsion between CTEs which stimulates t
he population of free carriers in higher energy states even at low tem
perature. The random distribution of excitons and finite Lifetime is e
xplicitly taken into account. The critical concentration of CTEs and t
heir energy distribution is calculated. Some features of spatial order
ing of CTEs at the interface are considered. We also discuss the possi
bility of observing the predicted phenomena. (C) 1998 Elsevier Science
B.V. All rights reserved.