THE 1 2 COMPLEX OF LICLO4 WITH BENZO-10-CROWN-3 ETHER AS STUDIED BY X-RAY CRYSTALLOGRAPHY AND SOLID-STATE C-13 NMR-SPECTROSCOPY - PSEUDOOCTAHEDRAL COORDINATION INVOLVING THE LITHIUM ION/

Authors
BUCHANAN GW GERZAIN M FACEY GA BENSIMON C
Citation
Gw. Buchanan et al., THE 1 2 COMPLEX OF LICLO4 WITH BENZO-10-CROWN-3 ETHER AS STUDIED BY X-RAY CRYSTALLOGRAPHY AND SOLID-STATE C-13 NMR-SPECTROSCOPY - PSEUDOOCTAHEDRAL COORDINATION INVOLVING THE LITHIUM ION/, Journal of molecular structure, 471(1-3), 1998, pp. 95-103
Citations number
13
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular structure → ACNP
ISSN journal
00222860
Volume
471
Issue
1-3
Year of publication
1998
Pages
95 - 103
Database
ISI
SICI code
0022-2860(1998)471:1-3<95:T12COL>2.0.ZU;2-Y
Abstract
In the title 2:1 crown:cation complex, Li+ is hexaacoordinate. The spa ce group of the crystal is P21/c, with a = 11.7842 (3), b = 14.1405 (4 ), c = 14.2322 (3), beta = 89.90 and Z = 4. The two benzo-10-crown-3 u nits are nonequivalent in the complex as a result of the spatial dispo sition of the anion and the C-13 CPMAS Spectrum is consistent with suc h a structure. (C) 1998 Elsevier Science B.V. All rights reserved.