Dm. Murphy et al., IN-SITU MEASUREMENTS OF ORGANICS, METEORITIC MATERIAL, MERCURY, AND OTHER ELEMENTS IN AEROSOLS AT 5 TO 19 KILOMETERS, Science, 282(5394), 1998, pp. 1664-1669
In situ measurements of the chemical composition of individual aerosol
particles at altitudes between 5 and 19 kilometers reveal that upper
tropospheric aerosols often contained more organic material than sulfa
te. Although stratospheric aerosols primarily consisted of sulfuric ac
id and water, many also contained meteoritic material. Just above the
tropopause, small amounts of mercury were found in over half of the ae
rosol particles that were analyzed. Overall, there was tremendous vari
ety in aerosol composition. One measure of this diversity is that at L
east 45 elements were detected in aerosol particles. These results hav
e wide implications for the complexity of aerosol sources and chemistr
y. They also offer possibilities for understanding the transport of at
mospheric aerosols.