PREPARATION OF RACEMIC 2,3-DIAMINOBUTANE AND THE RESOLUTION OF ITS (2S,3S) ENANTIOMER

Authors
SCAROS MG YONAN PK LANEMAN SA FERNANDO PN
Citation
Mg. Scaros et al., PREPARATION OF RACEMIC 2,3-DIAMINOBUTANE AND THE RESOLUTION OF ITS (2S,3S) ENANTIOMER, Tetrahedron : asymmetry, 8(9), 1997, pp. 1501-1506
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
8
Issue
9
Year of publication
1997
Pages
1501 - 1506
Database
ISI
SICI code
0957-4166(1997)8:9<1501:POR2AT>2.0.ZU;2-X
Abstract
A three-step procedure for large scale preparation of pure racemic 2,3 -diaminobutane from relatively inexpensive meso 2,3-butanediol is desc ribed. Also, an efficient method for the resolution of (S,S) 2,3-diami nobutane from the racemic mixture in <95% ee has been developed. (C) 1 997 Elsevier Science Ltd.