EXACTNESS AND APPLICABILITY LIMITS OF TROUTONS RULE

Authors
Citation
Ib. Sladkov, EXACTNESS AND APPLICABILITY LIMITS OF TROUTONS RULE, Russian journal of applied chemistry, 71(6), 1998, pp. 928-932
Citations number
8
Categorie Soggetti
Chemistry Applied
ISSN journal
10704272
Volume
71
Issue
6
Year of publication
1998
Pages
928 - 932
Database
ISI
SICI code
1070-4272(1998)71:6<928:EAALOT>2.0.ZU;2-D
Abstract
The theory of thermodynamic similarity is used to substantiate the lim its of applicability of Trouton's rule, Quantitative criteria are esta blished, ensuring reliable prognosis of the enthalpy of vaporization a t boiling point (Delta H-b) by Trouton's rule. Using the data obtained as a basis, a technique is proposed for evaluating the validity of pu blished Delta H-b values.