A NOVEL MACRODIOLIDE SYNTHESIS USING THE MN(III)-BASED RADICAL CYCLIZATION OF TERMINAL ALKADIENES AND OLIGOMETHYLENE DI(3-OXOBUTANOATE)S

Authors
YOSHINAGA T NISHINO H KUROSAWA K
Citation
T. Yoshinaga et al., A NOVEL MACRODIOLIDE SYNTHESIS USING THE MN(III)-BASED RADICAL CYCLIZATION OF TERMINAL ALKADIENES AND OLIGOMETHYLENE DI(3-OXOBUTANOATE)S, Tetrahedron letters, 39(50), 1998, pp. 9197-9200
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
50
Year of publication
1998
Pages
9197 - 9200
Database
ISI
SICI code
0040-4039(1998)39:50<9197:ANMSUT>2.0.ZU;2-P
Abstract
pha,omega,omega-Tetraphenyl-alpha,omega-alkadienes reacted with oligom ethylene di(3-oxobutanoate)s in the presence of manganese(III) acetate at 100 degrees C under an argon atmosphere to give new 12 to 22-membe red macrocyclic compounds which were two fused dihydrofuran rings in a one-step procedure. (C) 1998 Elsevier Science Ltd. All rights reserve d.