EFFECT OF HYBRIDIZATION ON THE ELECTRONIC-PROPERTIES OF CARBON BRIDGES

Authors
BENNISTON AC HARRIMAN A GROSSHENNY V ZIESSEL R
Citation
Ac. Benniston et al., EFFECT OF HYBRIDIZATION ON THE ELECTRONIC-PROPERTIES OF CARBON BRIDGES, New journal of chemistry, 21(4), 1997, pp. 405-408
Citations number
15
Categorie Soggetti
Chemistry
Journal title
New journal of chemistry → ACNP
ISSN journal
11440546
Volume
21
Issue
4
Year of publication
1997
Pages
405 - 408
Database
ISI
SICI code
1144-0546(1997)21:4<405:EOHOTE>2.0.ZU;2-V
Abstract
The extent of electronic coupling between remote metal complexes, as e xpressed in terms of electron delocalization, hole transfer, and rates of electron exchange, is comparable for ethenylene and ethynylene bri dges but is essentially non existent for ethanylene-bridging units.