Vk. Chebotarev et al., PROGNOSTICATION CRITERION OF POTENTIAL AND PRACTICAL USE OF ANALYTICAL REAGENTS IN TITRIMETRIA OF INDIVIDUAL SUBSTANCES, Talanta, 47(4), 1998, pp. 1043-1051
Various possible criterion in titrimetric methods have been discussed
in this paper and more informative, visual and universal criterion-the
degree of proceeding of individual reaction at the equivalence point
have been chosen. The equation for the degree of proceeding of individ
ual analytical reaction suited for any chemical reactions under real c
onditions with an allowance made for both component and titrant concen
tration have been deduced. This criterion allows us to make a prognosi
s of any parametres of a titrimetric procedure of an individual substa
nce determination and the procedure as a whole, not having carried out
the experiment. (C) 1998 Elsevier Science B.V. All rights reserved.