NOVEL LEWIS ACID-CATALYZED REARRANGEMENT OF A SUGAR-BASE HYBRID TO AFFORD AN ANHYDRONUCLEOSIDE

Authors
JUNG ME CASTRO C KHAN SI
Citation
Me. Jung et al., NOVEL LEWIS ACID-CATALYZED REARRANGEMENT OF A SUGAR-BASE HYBRID TO AFFORD AN ANHYDRONUCLEOSIDE, Nucleosides & nucleotides, 17(12), 1998, pp. 2383-2387
Citations number
14
Categorie Soggetti
Biology
Journal title
Nucleosides & nucleotides → ACNP
ISSN journal
07328311
Volume
17
Issue
12
Year of publication
1998
Pages
2383 - 2387
Database
ISI
SICI code
0732-8311(1998)17:12<2383:NLAROA>2.0.ZU;2-R
Abstract
Treatment of the sugar-base hybrid 9 with boron trichloride at low tem perature for 40 h affords the 6,3'-anhydro-2'-deoxyuridine 10 in 40% y ield (80% based on recovered 9) via a novel structural rearrangement.