IMPROVED EFFICIENT CONVERSION OF ALDEHYDES TO NITRILES VIA THEIR N,N-DIMETHYL HYDRAZONES

Authors
KAMAL A ARIFUDDIN M RAO NV
Citation
A. Kamal et al., IMPROVED EFFICIENT CONVERSION OF ALDEHYDES TO NITRILES VIA THEIR N,N-DIMETHYL HYDRAZONES, Synthetic communications, 28(24), 1998, pp. 4507-4512
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
28
Issue
24
Year of publication
1998
Pages
4507 - 4512
Database
ISI
SICI code
0039-7911(1998)28:24<4507:IECOAT>2.0.ZU;2-F
Abstract
Aldehyde N,N-dimethylhydrazones undergoes facile oxidative cleavage to nitriles on reaction with DIMS and K2CO3 in quantitative yields. Nitr iles can also be easily obtained in high yields in a 'one-pot' process starting from the corresponding aldehydes.