SYNTHETIC STUDIES DIRECTED TOWARD STREPTENOL-D - ENANTIOSELECTIVE PREPARATION OF THE 3,5-DIACETOXY-6E,8E-DECADIENE SEGMENT

Authors
DASGUPTA B DONALDSON WA
Citation
B. Dasgupta et Wa. Donaldson, SYNTHETIC STUDIES DIRECTED TOWARD STREPTENOL-D - ENANTIOSELECTIVE PREPARATION OF THE 3,5-DIACETOXY-6E,8E-DECADIENE SEGMENT, Tetrahedron : asymmetry, 9(21), 1998, pp. 3781-3788
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
9
Issue
21
Year of publication
1998
Pages
3781 - 3788
Database
ISI
SICI code
0957-4166(1998)9:21<3781:SSDTS->2.0.ZU;2-Y
Abstract
The enantioselective preparation of -(3'R,5'R-diacetoxy-6E,8E-decadien yl)-1,3-dioxane, (+)-13, is described. This synthesis of the skeleton of streptenol D utilizes the ability of a diene-complexed (tricarbonyl )iron unit to serve as a protecting and stereodirecting functionality. (C) 1998 Elsevier Science Ltd. All rights reserved.