B. Dasgupta et Wa. Donaldson, SYNTHETIC STUDIES DIRECTED TOWARD STREPTENOL-D - ENANTIOSELECTIVE PREPARATION OF THE 3,5-DIACETOXY-6E,8E-DECADIENE SEGMENT, Tetrahedron : asymmetry, 9(21), 1998, pp. 3781-3788
The enantioselective preparation of -(3'R,5'R-diacetoxy-6E,8E-decadien
yl)-1,3-dioxane, (+)-13, is described. This synthesis of the skeleton
of streptenol D utilizes the ability of a diene-complexed (tricarbonyl
)iron unit to serve as a protecting and stereodirecting functionality.
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