Am. Brockhoff et al., STRUCTURE AND HYDROGEN CONTENT OF STABLE HOT-WIRE-DEPOSITED AMORPHOUS-SILICON, Applied physics letters, 73(22), 1998, pp. 3244-3246
Thin-film transistors incorporating a hot-wire chemical-vapor-deposite
d silicon layer have been shown to exhibit superior electronic stabili
ty as compared to glow-discharge-deposited amorphous silicon devices.
Hot-wire-deposited silicon films of various thicknesses (37-370 nm) on
silicon dioxide were investigated. The films are structurally inhomog
eneous. Raman measurements and transmission electron microscopy show t
hat isolated cone-shaped crystals grow within a primarily amorphous la
yer. The amorphous interface region has a low hydrogen content of 2.0
+/- 0.2 at. %, while the films exhibit an enhanced hydrogen concentrat
ion in the surface region. The bond-angle distribution in the amorphou
s phase is comparable to that of device-quality glow-discharge-deposit
ed amorphous silicon. (C) 1998 American Institute of Physics. [S0003-6
951(98)01848-8].