S. Arai et al., CATALYTIC ASYMMETRIC EPOXIDATION OF NAPHTHOQUINONE DERIVATIVES UNDER PHASE-TRANSFER-CATALYZED CONDITIONS, Synlett, (11), 1998, pp. 1201
2-Alkyl-1,4-naphthoquinones were smoothly transformed to the correspon
ding epoxides in moderate to goad yields with good enantioselectivitie
s (up to 76% ee) under mild reaction conditions by use of a catalytic
amount of chiral quaternary ammonium salts derived from quinidine as a
phase-transfer catalyst.