SYNTHESIS OF AZASTEROIDS AND D-HOMOSTEROIDS BY INTRAMOLECULAR CYCLIZATION REACTIONS OF STEROID ARYLIMINES

Authors
WOLFLING J FRANK E SCHNEIDER G BES MT TIETZE LF
Citation
J. Wolfling et al., SYNTHESIS OF AZASTEROIDS AND D-HOMOSTEROIDS BY INTRAMOLECULAR CYCLIZATION REACTIONS OF STEROID ARYLIMINES, Synlett, (11), 1998, pp. 1205
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
11
Year of publication
1998
Database
ISI
SICI code
0936-5214(1998):11<1205:SOAADB>2.0.ZU;2-Q
Abstract
Intramolecular Lewis acid-catalyzed cyclization reactions of steroid a ryliminium salts 4a-e obtained from the secoestrone aldehyde 2 yield e ither the tetrahydroquinoline derivatives of estrone methyl ether 8a-d or the N-arylamino-D-homosteroids 7a-f, depending on the nature of th e substituent R at the aniline moiety in 4.