NUCLEOPHILIC SUBSTITUTIONS ON MULTIPIN(TM) SYSTEMS LINKED WITH A TRACELESS LINKER

Authors
TAKAHASHI T TOMIDA S INOUE H DOI T
Citation
T. Takahashi et al., NUCLEOPHILIC SUBSTITUTIONS ON MULTIPIN(TM) SYSTEMS LINKED WITH A TRACELESS LINKER, Synlett, (11), 1998, pp. 1261
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
11
Year of publication
1998
Database
ISI
SICI code
0936-5214(1998):11<1261:NSOMSL>2.0.ZU;2-L
Abstract
The displacement of polymer-supported glucose 7 at the 6-position by a zide, iodide, and acetate was achieved through a 4-hydroxybenzenesulfo nate-linked Multipin(TM) system giving the corresponding glucose deriv atives 8 in excellent yields. Macrocyclization of polymer-supported cy anohydrin ether 13 by displacement of the traceless sulfonate linker p rovided the cyclic compound 14 in moderate yield but in pure form.