A NEW, MODULATED, OXIDATIVE RING-CLEAVAGE OF ALPHA-NITROCYCLOALKANONES BY OXONE(R) - SYNTHESIS OF ALPHA,OMEGA-DICARBOXYLIC ACIDS AND ALPHA,OMEGA-DICARBOXYLIC ACID MONOMETHYL ESTERS (OCTOBER, PG 1149, 1998)

Authors
BALLINI R CURINI M EPIFANO F MARCOTULLIO MC ROSATI O
Citation
R. Ballini et al., A NEW, MODULATED, OXIDATIVE RING-CLEAVAGE OF ALPHA-NITROCYCLOALKANONES BY OXONE(R) - SYNTHESIS OF ALPHA,OMEGA-DICARBOXYLIC ACIDS AND ALPHA,OMEGA-DICARBOXYLIC ACID MONOMETHYL ESTERS (OCTOBER, PG 1149, 1998), Synlett, (11), 1998, pp. 3
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
11
Year of publication
1998
Database
ISI
SICI code
0936-5214(1998):11<3:ANMORO>2.0.ZU;2-O
Abstract
By the appropriate choice of the reaction conditions Oxone(R) produces the ring cleavage of alpha-nitrocyctoalkanones affording good yields of alpha,omega-dicarboxylic acids and alpha,omega-dicarboxylic acid mo nomethyl esters, respectively, regardless of the ring size and/or the presence of an alkyl group as substituent.