Cg. Li et al., SYNTHESIS AND CHARACTERIZATION OF BLOCK-C OPOLYMERS OF STYRENE AND METHYL-METHACRYLATE, Gaodeng xuexiao huaxue xuebao, 18(11), 1997, pp. 1879-1883
A series of diblock copolymers of styrene and methyl methacrylate were
synthesized via sequential anionic polymerization. The products are d
iblock copolymers with high molecular weight and narrow molecular weig
ht distribution. The microphase-separating structure is proved by the
information obtained from DMA and the solid state NMR. The morphology
structure is closely related to the ratio between (X) over bar(PMMA) a
nd (X) over bar(PS).