O. Bidault et al., EFFECTS OF LEAD VACANCIES ON THE SPONTANEOUS RELAXOR TO FERROELECTRICPHASE-TRANSITION IN PB[(MG1 3NB2/3)(0.9)TI-0.1]O-3/, Journal of applied physics, 82(11), 1997, pp. 5674-5679
We report electrical measurements in different Pb[(Mg1/3Nb2/3)(0.9)Ti-
0.1]O-3 ceramics exhibiting a spontaneous relaxer to ferroelectric tra
nsition. Both the relaxer behavior and the phase transition are found
to depend strongly on the lead vacancies content. An explanation based
on an increase of the ordered domains and lesser interactions between
polar clusters accounts for the experimental observations. (C) 1997 A
merican Institute of Physics.