ENHANCEMENT OF SULFATION OF MAGNESIUM BRIDE BY IRON-OXIDE

Authors
Citation
Ch. Cheng et Ci. Lin, ENHANCEMENT OF SULFATION OF MAGNESIUM BRIDE BY IRON-OXIDE, Journal of the Chinese Institute of Chemical Engineers, 28(5), 1997, pp. 359-367
Citations number
18
ISSN journal
03681653
Volume
28
Issue
5
Year of publication
1997
Pages
359 - 367
Database
ISI
SICI code
0368-1653(1997)28:5<359:EOSOMB>2.0.ZU;2-O
Abstract
The adsorption of SO2 by MgO pellet with Fe2O3 additive was investigat ed by thermogravimetric method. Surface areas, pore volumes and pore s ize distributions of pellet at different stages of reaction were deter mined by a surface area meter. The compositions of some solid samples were analyzed by X-ray diffractometer. Experimental results indicated that the reaction rate could be enhanced by increasing the amount of F e2O3, decreasing the grain size of Fe2O3 or increasing the sulfation t emperature. The enhancement of the adsorption of SO2 is probably due t o the catalytic effect of Fe2O3 on the oxidation of SO2 to form SO3 wh ich is captured by MgO.