SYNTHESIS AND STRUCTURE OF P-ASTERISK(3)(PH2C2S2)FE4S5)](BF4)CENTER-DOT-ME2CO - IMPLICATION OF THE FLEXIBLE FE4S5 FRAMEWORK

Authors
INOMATA S HITOMI K OGINO H
Citation
S. Inomata et al., SYNTHESIS AND STRUCTURE OF P-ASTERISK(3)(PH2C2S2)FE4S5)](BF4)CENTER-DOT-ME2CO - IMPLICATION OF THE FLEXIBLE FE4S5 FRAMEWORK, Chemistry Letters, (11), 1997, pp. 1169-1170
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
11
Year of publication
1997
Pages
1169 - 1170
Database
ISI
SICI code
0366-7022(1997):11<1169:SASOP>2.0.ZU;2-R
Abstract
A mixed ligand cluster, [Cp(3)(Ph2C2S2)Fe4S5](BF4). Me2CO, was synthe sized and its X-ray crystal structure was determined. From the compari son of this structure with those of Cp(3)(Ph2C2S2)Fe4S5 . THF, [Cp*(3 )(Ph2C2S2)Fe4S5](PF6). 2Me(2)CO, and [Cp(3)(Ph2C2S2)Fe4S5](PF6)(2) . Me2CO which have been reported previously, it is concluded that the Fe 4S5 core of the clusters is flexible and easily undergoes deformation.