REACTION OF HYDROSILANES WITH LITHIUM - FORMATION OF SILOLE ANIONS FROM 1-METHYLSILOLE VIA CARBODIANION

Authors
WAKAHARA T ANDO W
Citation
T. Wakahara et W. Ando, REACTION OF HYDROSILANES WITH LITHIUM - FORMATION OF SILOLE ANIONS FROM 1-METHYLSILOLE VIA CARBODIANION, Chemistry Letters, (11), 1997, pp. 1179-1180
Citations number
27
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
11
Year of publication
1997
Pages
1179 - 1180
Database
ISI
SICI code
0366-7022(1997):11<1179:ROHWL->2.0.ZU;2-8
Abstract
Three different types of silacyclopentadienyl anions have been obtaine d in the reduction of 1-methylsilole 1 with excess lithium. Treatment of lithiated solution with dimethylchlorosilane gave 2,5-bis(dimethyls ilyl)silole derivatives 3a and 3b, and with trimethylchlorosilane gave 1-trimethylsilyl-1-methylsilole derivative 4 at an early stage, and 1 ,1-bis(triemthylsilyl)silole derivative 8 at a late stage. Silole 1,1- dianion 7 has been formed via silole 2,5-dianion 2 and silole 1-anion 5.