Polymer induced epitaxy allows polymer epitaxy to be used not only for
growth of crystalline polymers but also in techniques for functionali
zing surfaces. A method is described by which it is possible to produc
e a crystalline polymer block epitaxially on a substrate with a non-cr
ystalline block-which can later be functionalized-anchored to the crys
talline block but not attached to the surface (see Figure).