The first manganese(II) compound with the saccharinate ligand present bothin the complex cation and as the counter-ion: [Mn(bipy)(2)(sac)(H2O)](+)center dot sac(-)

Authors
Dillon, KB Bilton, C Howard, JAK Hoy, VJ Deng, RMK Sethatho, DT
Citation
Kb. Dillon et al., The first manganese(II) compound with the saccharinate ligand present bothin the complex cation and as the counter-ion: [Mn(bipy)(2)(sac)(H2O)](+)center dot sac(-), ACT CRYST C, 55, 1999, pp. 330-332
Citations number
19
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
3
Pages
330 - 332
Database
ISI
SICI code
0108-2701(19990315)55:<330:TFMCWT>2.0.ZU;2-L
Abstract
The structure of the title compound, aqua[1,2-benzisothiazol- 3(2H)-onato 1 ,1-dioxide-N]bis(2,2'-bipyridine-N,N') manganese(II) 1,2-benzisothiazol-3 ( 2H)-onate 1,1-dioxide, [Mn(C7H4NSO3)(C10H8N2)(2)(H2O)](C7H4NSO3), consists of [Mn(bipy)(2)(sac)(H2O)](+) cations (bipy = 2,2'-bipyridine; sac = saccha rinate, C7H4NO3S) and non-coordinated saccharinate (sac(-)) anions. The Mn- II ion constitutes the centre of a slightly distorted octahedron, with the water molecule hydrogen bonded to the N atom in the saccharinate counter-io n.