A degraded glycol-substituted iso-closo ten-vertex ruthenaborane: [(PPh3)HClRuB9H5(OCH2CH2OH)(2)(PPh3)(2)]center dot 1.2CHCl(3)

Authors
Yao, HJ Hu, CH Dou, JM Sun, J Wei, JD Jin, RS Huang, ZE Zheng, PJ
Citation
Hj. Yao et al., A degraded glycol-substituted iso-closo ten-vertex ruthenaborane: [(PPh3)HClRuB9H5(OCH2CH2OH)(2)(PPh3)(2)]center dot 1.2CHCl(3), ACT CRYST C, 55, 1999, pp. 337-339
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
3
Pages
337 - 339
Database
ISI
SICI code
0108-2701(19990315)55:<337:ADGITR>2.0.ZU;2-#
Abstract
1-Chloro-1-hydrido-2,6-bis(2-hydroxyethoxy)-1,3,5-tris- (triphenylphosphine )-iso-closo-1-ruthenadecaborane-chloroform (1/1.2), [RuHCl(C40H45B9O4P2)(C1 8H15P)].-1.2CHCl(3), is a ruthenaborane based on an iso-closo C-3 nu stack, with the nine-coordinate metal occupying the six-connected apical position . The {RuB9} cage has two B-terminal -OCH2CH2OH groups and two PPh3 substit uents.