Trimethylphosphonium trichlorogermanate(II)

Authors
Kociok-Kohn, G Winter, JG Filippou, AC
Citation
G. Kociok-kohn et al., Trimethylphosphonium trichlorogermanate(II), ACT CRYST C, 55, 1999, pp. 351-353
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
3
Pages
351 - 353
Database
ISI
SICI code
0108-2701(19990315)55:<351:TT>2.0.ZU;2-1
Abstract
The title compound, [HPMe3][GeCl3], features pseudotetrahedral [HP(CH3)(3)] (+) and trigonal-pyramidal GeCl3- units that form a strongly distorted pero vskite structure. The Ge-II centre shows a distorted octahedral environment with three short Ge-Cl bonds [average Ge-Cl = 2.3071 (9) Angstrom] and thr ee much longer interionic Ge ... Cl distances [average Ge ... Cl = 4.1372 ( 12) Angstrom].