Lead(II) oxydiacetate hydrate

Citation
S. Norberg et al., Lead(II) oxydiacetate hydrate, ACT CRYST C, 55, 1999, pp. 356-358
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
3
Pages
356 - 358
Database
ISI
SICI code
0108-2701(19990315)55:<356:LOH>2.0.ZU;2-0
Abstract
The coordination polyhedron around the Pb atom in the title compound, poly[ aqualead(II)-mu(5)-oxydiacetato], [Pb(mu(5)-C4H4O5)(H2O)](n), is a distorte d square antiprism formed by three O atoms from one oxydiacetate ligand, fo ur O atoms from four other identical ligands and one water O atom, resultin g in a three-dimensional network structure. The almost planar oxydiacetate ligand is disordered over two positions. The Pb lone-pair 6s(2) electrons s how stereochemical activity in the coordination sphere.