Triaquabis(nitrato-O,O ')(2,2 ': 6 ',2 ''-terpyridine-kappa N-3)gadalinium(III) nitrate

Authors
Leverd, PC Charbonnel, MC Dognon, JP Lance, M Nierlich, M
Citation
Pc. Leverd et al., Triaquabis(nitrato-O,O ')(2,2 ': 6 ',2 ''-terpyridine-kappa N-3)gadalinium(III) nitrate, ACT CRYST C, 55, 1999, pp. 368-370
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
3
Pages
368 - 370
Database
ISI
SICI code
0108-2701(19990315)55:<368:T''6''>2.0.ZU;2-N
Abstract
Gadolinium nitrate forms a complex with terpyridine at the interface betwee n an aqueous solution of the metal cation and a chloroform solution of the organic ligand. The title complex, [Gd(terpy)(NO3)(2)(H2O)(3)]NO3 (terpy = terpyridine, C15H11N3), is ten-coordinate and its coordination polyhedron c an be described as a distorted bicapped square antiprism. The coordinated n itrates are bidentate. The three water ligands form hydrogen bonds in the l attice.