1-nitrobenzo[c]cinnoline

Citation
T. Hokelek et al., 1-nitrobenzo[c]cinnoline, ACT CRYST C, 55, 1999, pp. 383-385
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
3
Pages
383 - 385
Database
ISI
SICI code
0108-2701(19990315)55:<383:1>2.0.ZU;2-U
Abstract
The title compound, C12H7N3O2, is a 1-nitro derivative of the ligand benzo[ c]cinnoline. The rings in the benzo[c]cinnoline skeleton are close to plana rity, while the skeleton itself is non-planar. The dihedral angles between the rings in the benzo[c]cinnoline skeleton are alpha<^>beta 4.0(5), alpha< ^>gamma 8.4(2) and beta<^>gamma 4.5(4)degrees; in benzo[c]cinnoline the alp ha<^>gamma dihedral angle is 2.5 degrees. The difference is caused by steri c interactions between the nitro group and benzo[c]cinnoline skeleton.