6-[N-(2-hydroxyphenyl)aminomethylene]-cyclohexa-2,4-dien-1-one

Citation
Ak. Mukherjee et al., 6-[N-(2-hydroxyphenyl)aminomethylene]-cyclohexa-2,4-dien-1-one, ACT CRYST C, 55, 1999, pp. 407-410
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
3
Pages
407 - 410
Database
ISI
SICI code
0108-2701(19990315)55:<407:6>2.0.ZU;2-8
Abstract
The structure determination of the title compound, C13H11NO2, establishes t he tautomeric keto form of the salicylaldimine. The asymmetric unit consist s of two crystallographically independent molecules which are essentially p lanar and are approximately orthogonal to each other. Strong intramolecular N-H ... O and intermolecular O-H ... O interactions influence the conforma tion of the molecules and the crystal packing. Intermolecular hydrogen bond s link the molecules in infinite chains.