A stereoselective reductive rearrangement of allylic epoxyalcohols - New synthetic method of 1,3-diol

Authors
Tu, YQ Xia, WJ Wang, PZ Zhai, JJ Chen, YZ
Citation
Yq. Tu et al., A stereoselective reductive rearrangement of allylic epoxyalcohols - New synthetic method of 1,3-diol, CHEM J CH U, 20(4), 1999, pp. 587-589
Citations number
9
Categorie Soggetti
Chemistry
Journal title
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN journal
02510790 → ACNP
Volume
20
Issue
4
Year of publication
1999
Pages
587 - 589
Database
ISI
SICI code
0251-0790(199904)20:4<587:ASRROA>2.0.ZU;2-9
Abstract
A novel method for synthesis of stereoselective 1,3-diol from alpha-hydroxy epoxides was developed by reductive rearrangement with aluminum isopropoxid e, which is very convenient and efficient. The substituted effect and stere ochemistry were also discussed.